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There are five types of adsorption isotherms possible. The characterization of microporous materials, those with pore diameters less than 2 nm, gives this type of isotherm.

The flatter region in the middle represents the formation of a monolayer. This is the most common isotherm obtained when using the BET technique.

At very low pressures, the micropores fill with nitrogen gas. At the knee, monolayer formation is beginning and multilayer formation occurs at medium pressure.

At the higher pressures, capillary condensation occurs. Because there is no asymptote in the curve, no monolayer is formed and BET is not applicable.

Gases condense in the tiny capillary pores of the solid at pressures below the saturation pressure of the gas. At the lower pressure regions, it shows the formation of a monolayer followed by a formation of multilayers.

BET surface area characterization of mesoporous materials, which are materials with pore diameters between 2 - 50 nm, gives this type of isotherm.

STP is defined as K and 1 atm. At relative pressures higher than 0. When the BET equation is plotted, the graph should be of linear with a positive slope.

If such a graph is not obtained, then the BET method was insufficient in obtaining the surface area. Single point BET can also be used by setting the intercept to 0 and ignoring the value of C.

The data point at the relative pressure of 0. Prior to any measurement the sample must be degassed to remove water and other contaminants before the surface area can be accurately measured.

Samples are degassed in a vacuum at high temperatures. IUPAC recommends that samples be degassed for at least 16 hours to ensure that unwanted vapors and gases are removed from the surface of the sample.

Generally, samples that can withstand higher temperatures without structural changes have smaller degassing times.

A minimum of 0. This is a simple example:. Even if our opponent did hold a hand like QQ or AJ, it is very difficult for them to call for the fear of us holding Aces or Kings, which is why the continuation bet brings home so much money due to the 3-bet before the flop.

This article is one of the longest I have ever written, yet I still feel that it could have been a bit meatier. Congratulations if you made it this far, and I hope most of it made sense and you can understand the theory behind 3-betting lightly and how it can be profitable.

Just be sure not to abuse 3-betting and you will be fine. I'd recommend dropping down a level to experiment with 3-betting and to find your feet with it.

It's definitely a skill that is worth perfecting and adding to your game as a mid-stakes player or for when you reach those levels.

It's an excellent strategy video for playing in tricky 3bet spots. SwC Poker is my favourite room to play at.

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Accepting players from: France. Home Strategy Plays 3bet Strategy. The 3-Bet By Greg Walker The 3-bet or more specifically, light 3-betting is an advanced concept that adds an extra weapon to a game that has likely become repetitive and stagnant, even if that current game strategy is winning you money at the tables.

What is 3-betting? Why 3-bet? When and where to 3-bet light. How to 3-bet effectively. This will involve using a polarized range.

The percentages of fold to 3-bet work on a sliding scale. This statistic can change the way that you create your ranges.

Against players who have a high fold to flop continuation bet, you can start opening your range to have a slightly higher concentration of bluffs.

Be wary of 3-betting a player who has a high 4-bet percentage. Against these players, you can develop a strategy of 3-betting a tighter range and 5-betting them which is often an all-in preflop if they are calling too much, or flat calling their 4-bets with your range advantage and playing postflop.

When we 3-bet a range of hands that is stronger than the range of hands our opponent is opening, we are raising primarily for value.

This is called a depolarized strategy. A depolarized range only contains value hands of varying strength. Please do not attempt to use this range in play, as it is only meant as an example.

We balance this range depending on their fold to 3-bet poker statistics. This is called a polarized strategy. You would be 3-betting A2s—A5s as a bluff, and planning on folding to a 4-bet.

In this situation, you have 16 combos of hands that are bluffs, and 34 that are value, which is a good range for beginners to become more comfortable.

Please do not use this 3-betting range in your games; it is only an example meant to illustrate how a 3-betting range can be constructed.

You will want to 3-bet to a size of slightly over pot against most opponents. Against players who are folding too often against 3-bets, you can use a slightly smaller sizing and add in more bluffs.

Against players calling too often against 3-bets, you can use a slightly larger sizing, and have a higher ratio of value to bluffs. The small blind is the most difficult blind to defend.

This is because if you flat call preflop, the player in the big blind will have a very good price to call compared to the size of the pot.

The use of 3-bets is best done selectively , at opportune moments. Many hyper-aggressive players 3-bet with a wide range of hands, including many garbage hands, in the nature of bluffs.

Most 3-bets, however, are done with big hands. Another successful type of 3-bet can be done against a player who might over-value the long-term prospects of the game or tourney in deference to what might happen in that specific hand.

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